Reactions of Dicyanogen and Cyanogen Halides with the Biscyclopentadienyls of Vanadium and Chromium
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چکیده
The oxidative addition of dicyanogen, (CN)2, and of the cyanogen halides, XCN (X = Cl, Br or I), to the biscyclopentadienyl compounds of vanadium and chromium, (/y-C^Hs^M (M = V or Cr), leads to the formation of (/?-C5H5)2MX(CN) (X = CN, Cl, Br, I ; M = V or Cr). The synthesized compounds have been characterized by elemental analyses, IR and EPR spectra, and determinations of the magnetic moments.
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تاریخ انتشار 2012